Revisiting the conformational analysis of unsaturated organic compounds using the bent bond / antiperiplanar hypothesis
The bent bond/antiperiplanar hypothesis (BBAH) offers a straightforward qualitative model for interpreting the conformational analysis of simple unsaturated acyclic systems, as well as cyclohexene and methylenecyclohexane derivatives. The torsional profiles of a series of unsaturated compounds were computed by MP2 calculations, and their relative conformational outcomes were interpreted using the BBAH model.
BBAH #16: G. Deslongchamps, N. Vatcher, P. Deslongchamps, Revisiting the conformational analysis of unsaturated organic compounds using the bent bond / antiperiplanar hypothesis, Tetrahedron, 2021, 92, 132249-132256.
https://doi.org/10.1016/j.tet.2021.132249
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