Bent Bonds and the Antiperiplanar Hypothesis. A Model to Account for Sigmatropic [1,n]-Hydrogen Shifts
Sigmatropic hydrogen shifts are rationalized using the BBAH involving antiperiplanar displacement of radical intermediates. The stereochemistry of both thermal and photochemical processes is described.
BBAH #7: G.Deslongchamps, P. Deslongchamps, Bent Bonds and the Antiperiplanar Hypothesis. A Model to Account for Sigmatropic [1,n]-Hydrogen Shifts. J. Org. Chem., 2018, 83, 10383-10388.
https://doi.org/10.1021/acs.joc.8b01472
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