BBAH

BBAH paper #4

Bent Bonds and the Antiperiplanar Hypothesis and the Reactivity at the Anomeric Center in Pyranosides A solo contribution from the P. Deslongchamps group. The stereoselectivity of nucleophilic addition on oxocarbenium ions derived from the bicyclic […]

BBAH

BBAH paper #3

Bent Bonds and the Antiperiplanar Hypothesis – A Simple Model to Rationalize [1,3]-Sigmatropic Alkyl Shifts The bent bond/antiperiplanar (BBA) hypothesis has been applied to the analysis of [1,3]-sigmatropic alkyl shifts. These thermal rearrangements, for which […]